Reversible and Quasireversible Electron Transfer under Conditions of Differential Square-Wave Voltammetry

A theoretical analysis of reversible and quasireversible electrode reactions a dissolved redox couple under conditions the novel technique differential square-wave voltammetry (DSWV) is presented. The recently introduced as hybrid form between pulse (DPV) (SWV) two most advanced competitive pulse-form voltammetric techniques for purpose unifying their advantages further advancing both in terms analytical performances, mechanistic analysis, kinetics. potential modulation DSWV consists steps pulses providing plethora curves, which enable in-depth characterization reaction with minimal set measurements. Based on numerical simulations, criteria differentiation are established.